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Beilstein J. Org. Chem. 2010, 6, 773–783, doi:10.3762/bjoc.6.96
Graphical Abstract
Figure 1: Schematic representation of the investigated strategy for the synthesis of star-shaped poly(2-ethyl...
Scheme 1: General reaction scheme for the preparation of multi-tosylates from multifunctional alcohols (top) ...
Figure 2: MALDI-TOF MS spectra of TetraTos a) and HexaTos b) Matrix: dithranol.
Figure 3: Molecular structure a) and packing diagram b) of the structure of diethyleneglyclol ditosylate (DiT...
Figure 4: Molecular structure a) and packing diagram b) of the structure of 1,4-butanediol ditosylate (DiTos-...
Figure 5: Molecular structure a) and packing diagram b) of the structure of penthaerythritol tetra-tosylate (...
Figure 6: Molecular structure a) and packing diagram b) of the structure of dipenthaerythritol tetra-tosylate...
Figure 7: SEC traces obtained for the polymerization of 2-ethyl-2-oxazoline initiated with TetraTos a) and He...
Scheme 2: Schematic representation of the synthesis of a porphyrin initiated four-armed star-pEtOx starting f...
Figure 8: MALDI-TOF MS spectrum of the tetra-tosylate-porphyrin (TetraTos-B). Matrix: dithranol.
Figure 9: a) 1H NMR spectra (in CDCl3) of the porphyrin initiator TetraTos-B (bottom) and star-pEtOx (top). b...
Figure 10: SEC spectrum obtained for star-pEtOx utilizing a photodiode-array detector (eluent: DMF containing ...